I don't teach or recommend so-called "purely positive" methods that allow misbehaving pups to continue misbehaving, instead of teaching them which behaviors are and are not allowed. "Purely positive" is fine for teaching tricks and high-level competition exercises, but NOT for teaching the solid good behaviors that all family dogs need to know, and NOT for stopping behavior problems such as barking, jumping, chewing, nipping, chasing, etc.
It's not so much the dog doesn't listen, more that he doesn't understand what you want him to do. Go back to basics and don't punish him when he toilets indoors. Double your vigilance and take every opportunity to put him outside to toilet. The crucial thing is to be present when he does toilet in the correct place, so that you can reward him. This makes him keener to repeat the performance to get another treat. Conversely, if you have been telling him off for indoor accidents he may already feel inhibited about going to the toilet in your presence, including when he goes outdoors. This is one reason why it's important not to punish for inappropriate toileting.
You may also notice common behavior problems in your dog such as jumping up, barking, or even aggression. The best way to correct any misbehavior is to interrupt it. Shift your dog's attention to something positive. Try running through cues that your dog has mastered followed by rewards. Keep your demeanor cool and confident, and be clear about what you mean.
If your dog isn’t giving you an obvious signal that they need to go out (like whining at the door) I suggest teaching them to ring a bell when they need to go outside. Some of the other signs dogs give that they need to go out such as pacing around or circling can be easy to miss if they’re in another room, which is why a noise based signal such as ringing a bell can make things easier.